JEE Main Electrochemistry — practice questions
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In the Daniell cell shown, which metal acts asFor a galvanic cell, the standard cell EMF is given by:Given standard reduction potentials $E^{\circ}(\mathrm{Cu^{2+}/Cu}) = +0.34$ V and $E^{\circ}(\mathrm{Zn^{2+}/The Nernst equation for a half-cell reaction at 298 K is:How many coulombs of charge are required to deposit $108$ g of silver from a $\mathrm{AgNO_3}$ solution? (AtomWhen a current of $5$ A is passed through a $\mathrm{CuSO_4}$ solution for $193$ seconds, the mass of Cu deposA device converting CHEMICAL energy to electrical energy via spontaneous redox is a:In the Daniell cell, the cathode reaction is:EMF of standard Daniell cell at 25°C is approximately:Faraday's first law of electrolysis states mass deposited is proportional to:The value of Faraday's constant F is approximately:In a galvanic cell, electrons flow externally from:The Nernst equation gives cell EMF at non-standard conditions. For a half-cell Mⁿ⁺ + ne⁻ → M, it is:Relation between standard cell potential E°, ΔG°, and equilibrium constant K:For ΔG° < 0 (spontaneous), E° must be:The molar conductivity Λ_m of an electrolyte:Kohlrausch's law states the limiting molar conductivity of an electrolyte is:For the cell Zn | Zn²⁺ (1 M) || Cu²⁺ (1 M) | Cu, with E°(Zn) = -0.76 V, E°(Cu) = +0.34 V, E_cell:Standard electrode potential of SHE (Standard Hydrogen Electrode) is taken as:For Cu²⁺ + 2e⁻ → Cu, how much charge to deposit 0.5 mol Cu? (F = 96500 C/mol)Conductivity κ of pure water is approximately:At 25°C, ratio of Nernst factor 0.0591/n to RT/(nF) ln 10 in SI units:A current of 2 A flows for 30 min through a CuSO4 solution. Mass of Cu deposited (M_Cu = 63.5):For the cell: Zn|Zn²⁺(0.1 M)||Cu²⁺(0.01 M)|Cu, at 25°C, E_cell is:Equilibrium constant K of the Daniell cell at 25°C (E° = 1.10 V, n = 2):A 0.1 M weak acid HA has Λ_m = 10 S·cm²/mol; at infinite dilution Λ_m^0 = 400. Degree of dissociation α:In electrolysis of CuSO4 with Pt electrodes, the cathode product is:Standard electrode potentials: E°(Fe³⁺/Fe²⁺) = +0.77 V, E°(I2/I⁻) = +0.54 V. For the reaction 2Fe³⁺ + 2I⁻ → 2FWhy is the cell potential temperature-dependent?For Hg²⁺/Hg (E° = +0.79 V) and Cu²⁺/Cu (E° = +0.34 V), the spontaneous reaction is:Conductivity of a 0.01 M NaCl solution is 0.0014 S/cm. Molar conductivity Λ_m:Lead-acid battery during DISCHARGE: PbO2 + Pb + 2H2SO4 → 2PbSO4 + 2H2O. The role of PbO2 is:Corrosion of iron involves which type of reaction?In electroplating silver onto a spoon, the cathode is:Electrochemistry deals with:In a galvanic (voltaic) cell, oxidation occurs at:Standard electrode potential of standard hydrogen electrode (SHE) is:In Daniell cell (Zn | Zn²⁺ || Cu²⁺ | Cu), electron flow in external circuit:Faraday's first law of electrolysis: amount of substance liberated at electrode is proportional to:Conductance is the:Nernst equation for cell potential (at 25°C):For Daniell cell, cell reaction Zn + Cu²⁺ → Zn²⁺ + Cu. Cell EMF:Faraday constant F is:Standard Gibbs free energy and cell EMF relation:Relation between equilibrium constant K and E°:How many coulombs are needed to deposit 1 mole of Cu from CuSO₄ (Cu²⁺ + 2e⁻ → Cu)?Time to deposit 1.27 g of Cu from CuSO₄ solution at 2 A current (Cu atomic mass = 63.5):Equilibrium constant for cell with E° = 0.118 V, n = 2, at 25°C:Specific conductance κ has units:Hydrogen-Oxygen fuel cell produces:Lead acid battery (used in cars) overall reaction:Standard reduction potential ranking. Which is the strongest oxidizing agent?Resistance of a conductivity cell filled with 0.1 M KCl is 100 Ω. Specific conductivity κ of solution (cell coFor a cell reaction reversed in direction, E° becomes:In a Daniell cell with Zn (anode) and Cu (cathode), and $E^\circ(Cu^{2+}/Cu) = +0.34$ V, $E^\circ(Zn^{2+}/Zn) The Nernst equation at $25^\circ$C for a cell with $n$ electrons transferred is $E = E^\circ -$:Electrolysis of molten NaCl at the electrode passes $1$ F of charge. The amount of Na deposited at the cathodeIron rusting on the village ploughshare is best described as:In a GALVANIC cell, the ANODE is:The standard electrode potential of the Standard Hydrogen Electrode (SHE) is defined as:The Daniell cell (Zn-Cu) has E°cell = +1.10 V. Calculate ΔG° (F = 96500 C/mol):The Nernst equation at 25°C for a cell reaction is:Kohlrausch's law is most useful for determining the LIMITING molar conductivity (Λ°m) of:Faraday's first law of electrolysis states that the mass deposited is:A typical LEAD STORAGE BATTERY (car battery) used in vehicles consists of 6 cells in series, each producing abThe byproduct of a hydrogen-oxygen fuel cell (used in space + electric cars) is:GALVANISATION protects iron from rusting by coating it with:The standard EMF of a Zn|Zn²⁺||Cu²⁺|Cu cell (E°_Cu²⁺/Cu = +0.34 V; E°_Zn²⁺/Zn = −0.76 V) isThe Nernst equation for a cell reaction at 298 K is E_cell = E°_cell − (0.059/n) log Q. Here n isFor the reaction Cu²⁺ + 2e⁻ → Cu with E° = +0.34 V, what is the cell potential when [Cu²⁺] = 0.01 M at 298 K?One Faraday equals the charge onThe mass of copper deposited when a current of 5.0 A flows for 30 minutes through a solution of CuSO₄ (M_Cu = Kohlrausch's law of independent migration of ions is used to computeFor a Cu-Zn Daniell cell, the emf is measured to be 1.10 V under standard conditions. If [Cu²⁺] = 1 M and [Zn²Molar conductivity of a strong electrolyte at concentration c is related to its limiting value Λ°_m by the DebThe specific conductivity of a 0.1 M KCl solution is 1.29 × 10⁻² S/cm. The molar conductivity isFuel cells directly convertRusting of iron requires which two chemicals in contact with the metal?The primary cell that cannot be reused after its EMF drops to zero is exemplified byThe overall cell reaction of the lead storage battery on discharge isWhich of the following statements about electrode potentials is INCORRECT?For an electrochemical cell operating spontaneously, ΔG° is related to E°_cell by