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CG PET Chemical Kinetics — practice questions

Explore 75 free Chemical Kinetics questions in CG PET Chemistry. Open each question or exercise to read its content, reference answers and available explanation.

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Chemical Kinetics questions and exercises with answers

Showing questions 1–30 of 75.

The SI/CGS-style units of the **rate of a chemical reaction** are:Read the answer and worked solution →For the reaction A → B, the rate of reaction can be written as:Read the answer and worked solution →The **rate constant** $k$ in a rate law equals the rate of reaction when:Read the answer and worked solution →The order of a reaction:Read the answer and worked solution →For a zero-order reaction, the units of the rate constant $k$ are:Read the answer and worked solution →For a first-order reaction, the units of the rate constant $k$ are:Read the answer and worked solution →For the same reaction ($2N_2O_5 \to 4NO_2 + O_2$, $d[N_2O_5]/dt = -0.02$), the **rate of formation of $NO_2$** is:Read the answer and worked solution →If rate = $k[A][B]^2$, what are the units of $k$?Read the answer and worked solution →For the reaction A + B → P with $\text{rate} = k[A][B]^2$, rate = $3.6 \times 10^{-2}$ mol dm⁻³ s⁻¹ when [A] = 0.2 M and [B] = 0.1 M. $k$ equals:Read the answer and worked solution →For the reaction R → P, the *instantaneous* rate of reaction is given by:Read the answer and worked solution →For the reaction 2HI(g) → H₂(g) + I₂(g), the rate of reaction is:Read the answer and worked solution →The SI unit of rate of a reaction is:Read the answer and worked solution →The rate law for a reaction must be:Read the answer and worked solution →The units of the rate constant k for a zero-order reaction are:Read the answer and worked solution →The units of the rate constant k for a first-order reaction are:Read the answer and worked solution →A rate constant has units of L mol⁻¹ s⁻¹. The order of the reaction is:Read the answer and worked solution →For a zero-order reaction R → P, the integrated rate equation is:Read the answer and worked solution →For a first-order reaction, the half-life t_(1/2) is:Read the answer and worked solution →All radioactive decays follow which order of kinetics?Read the answer and worked solution →A first-order reaction with rate constant k = 5.5 × 10⁻¹⁴ s⁻¹ has a half-life of approximately:Read the answer and worked solution →For a chemical reaction, with a rise in temperature by 10°C, the rate of reaction typically:Read the answer and worked solution →The Arrhenius equation is:Read the answer and worked solution →On a plot of ln k versus 1/T (Arrhenius plot), what is the slope?Read the answer and worked solution →In the Arrhenius equation, the pre-exponential factor A is also called:Read the answer and worked solution →For a first-order reaction, the time required for 99.9% completion is approximately:Read the answer and worked solution →For a first-order reaction, if the initial concentration of N₂O₅ is 1.24 × 10⁻² mol L⁻¹ and after 60 min it is 0.20 × 10⁻² mol L⁻¹, the rate constant k is approximately:Read the answer and worked solution →For a zero-order reaction, if the initial concentration is doubled, the half-life:Read the answer and worked solution →Time required to decompose SO₂Cl₂ to half of its initial amount is 60 min. Assuming first-order kinetics, the rate constant is:Read the answer and worked solution →Rate of reaction is defined as:Read the answer and worked solution →Rate law: r = k [A]ᵐ [B]ⁿ. Sum m + n is called:Read the answer and worked solution →

Worked practice questions

The SI/CGS-style units of the **rate of a chemical reaction** are:

  1. L mol⁻¹ s⁻¹
  2. mol dm⁻³ s⁻¹
  3. mol L⁻¹
  4. s⁻¹
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Correct answer: B. mol dm⁻³ s⁻¹

Rate = change in concentration / change in time, hence units are concentration/time = mol dm⁻³ s⁻¹ (or mol L⁻¹ s⁻¹).

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For the reaction A → B, the rate of reaction can be written as:

  1. $-d[A]/dt$ only
  2. $+d[B]/dt$ only
  3. $+d[A]/dt = -d[B]/dt$
  4. $-d[A]/dt = +d[B]/dt$
Show answer and solution

Correct answer: D. $-d[A]/dt = +d[B]/dt$

A is consumed → rate $= -d[A]/dt$ (negative because [A] decreases). B is formed → rate $= +d[B]/dt$. By stoichiometry (1:1), both are equal.

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The **rate constant** $k$ in a rate law equals the rate of reaction when:

  1. All reactant concentrations are zero
  2. All reactant concentrations are unity
  3. Temperature is zero kelvin
  4. Time is zero
Show answer and solution

Correct answer: B. All reactant concentrations are unity

Putting unit concentrations into rate = $k[A]^x[B]^y$ gives rate = $k$. **So $k$ is the rate at unit concentrations of all reactants.**

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