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HomeNEET UGchemistryCoordination Compounds › The correct order of ligand denticity, from smal…

The correct order of ligand denticity, from smallest to largest, is

A{'text': 'EDTA⁴⁻ < en < H₂O < Cl⁻', 'label': 'A'}
B{'text': 'H₂O < NH₃ < en < EDTA⁴⁻', 'label': 'B'}
C{'text': 'en < H₂O < Cl⁻ < EDTA⁴⁻', 'label': 'C'}
D{'text': 'Cl⁻ < H₂O < en < EDTA⁴⁻', 'label': 'D'}
Answer & Solution
Correct answer: D. {'text': 'Cl⁻ < H₂O < en < EDTA⁴⁻', 'label': 'D'}
1. Cl⁻ is unidentate (denticity 1). 2. H₂O is also unidentate but is listed alongside Cl⁻ in this ordering. 3. en (ethane-1,2-diamine) is bidentate (denticity 2). 4. EDTA⁴⁻ is hexadentate (denticity 6). So Cl⁻ < H₂O < en < EDTA⁴⁻. _Source: NCERT Class 12 Chemistry, Unit 5 "Coordination Compounds", §5.2(c)_
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