The coordination sphere of K₄[Fe(CN)₆] is
A{'text': 'The [Fe(CN)₆]⁴⁻ inner-bracket group', 'label': 'A'}
B{'text': 'The four K⁺ counter ions', 'label': 'B'}
C{'text': 'The six free CN⁻ ligand molecules', 'label': 'C'}
D{'text': 'The overall neutral K₄Fe skeleton', 'label': 'D'}
Answer & Solution
Correct answer: A. {'text': 'The [Fe(CN)₆]⁴⁻ inner-bracket group', 'label': 'A'}
1. NCERT defines the coordination sphere as central atom + ligands in square brackets.
2. In K₄[Fe(CN)₆] the square-bracketed entity is [Fe(CN)₆]⁴⁻.
3. K⁺ ions outside the bracket are counter ions, not part of the coordination sphere.
4. So [Fe(CN)₆]⁴⁻ is the coordination sphere.
_Source: NCERT Class 12 Chemistry, Unit 5 "Coordination Compounds", §5.2(e)_
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