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For 1 mol of CoCl₃·4NH₃ (green or violet isomer), moles of AgCl precipitated by excess AgNO₃ is
A{'text': '0', 'label': 'A'}
B{'text': '1', 'label': 'B'}
C{'text': '2', 'label': 'C'}
D{'text': '3', 'label': 'D'}
Answer & Solution
Correct answer: B. {'text': '1', 'label': 'B'}
1. Formula is [CoCl₂(NH₃)₄]Cl.
2. Only 1 chloride sits outside the coordination sphere (ionisable).
3. So only 1 mol AgCl precipitates per mol.
4. The complex is a 1:1 electrolyte.
_Source: NCERT Class 12 Chemistry, Unit 5 "Coordination Compounds", §5.1_
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