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The COORDINATION NUMBER of the central metal in a complex is
Athe total charge on the complex ion
Bthe number of LIGAND ATOMS DIRECTLY BONDED to the metal
Cthe oxidation state of the metal
Dthe atomic number of the metal element
Answer & Solution
Correct answer: B. the number of LIGAND ATOMS DIRECTLY BONDED to the metal
1. NCERT §5.2 defines coordination number (CN) explicitly.
2. CN is the NUMBER OF LIGAND DONOR ATOMS that are directly bonded to the central metal — not the number of ligand molecules, in case of polydentate ligands.
3. Example: $[\mathrm{Co(NH_3)_6}]^{3+}$ has six ammonia ligands, each contributing one nitrogen — CN = 6.
4. Example: $[\mathrm{Co(en)_3}]^{3+}$ has three ethylenediamine ligands (bidentate, each contributing two nitrogens) — CN = 6 as well.
5. Common CN values: 2, 4, 6 (most common for d-block), with some examples up to 8.
6. Option A is the complex charge, not the CN. Option C is the oxidation state (a separate property). Option D is the atomic number (irrelevant to coordination).
_Source: NCERT Class 12 Chemistry Part 1, Ch 5, §5.2 (Definitions — coordination number), p. 2–3._
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