A **cross aldol** condensation between benzaldehyde and acetone (excess acetone) gives, as the major product,
- Acetophenone
- 4-Phenyl-3-buten-2-one
- Dibenzalacetone (only)
- Cinnamaldehyde
Show answer and solution
Correct answer: B. 4-Phenyl-3-buten-2-one
Acetone has $\alpha$-H, benzaldehyde does not (so benzaldehyde cannot form an enolate — only acetone can).
Excess acetone gives mono-condensation product $C_6H_5CH=CHCOCH_3$ (4-phenyl-3-buten-2-one).
With excess benzaldehyde, both methyls of acetone react to give dibenzalacetone.