Nitrate is leached from soil more readily than ammonium because nitrate:
- is a cation attracted to soil colloids
- is an anion repelled by soil colloids
- is far heavier than the ammonium ion
- dissolves far less readily in water
Show answer and solution
Correct answer: B. is an anion repelled by soil colloids
1. Soil colloids, the clay and humus particles, carry a net negative charge.
2. Ammonium, $NH_4^+$, is a cation, so those negative sites attract and hold it by cation exchange.
3. Nitrate, $NO_3^-$, is an anion, so the same negative sites repel it.
4. Having nothing to hold it, nitrate stays free in the soil water.
5. Draining water therefore washes nitrate down through the profile, which is leaching.
_Source: NECTA ACSEE 2024 Chemistry 132/1, Question 8: Soil Chemistry and Environmental Chemistry_