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Nitrate is leached from soil more readily than ammonium because nitrate:
Ais a cation attracted to soil colloids
Bis an anion repelled by soil colloids
Cis far heavier than the ammonium ion
Ddissolves far less readily in water
Answer & Solution
Correct answer: B. is an anion repelled by soil colloids
1. Soil colloids, the clay and humus particles, carry a net negative charge.
2. Ammonium, $NH_4^+$, is a cation, so those negative sites attract and hold it by cation exchange.
3. Nitrate, $NO_3^-$, is an anion, so the same negative sites repel it.
4. Having nothing to hold it, nitrate stays free in the soil water.
5. Draining water therefore washes nitrate down through the profile, which is leaching.
_Source: NECTA ACSEE 2024 Chemistry 132/1, Question 8: Soil Chemistry and Environmental Chemistry_
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