Inert pair effect causes stability of:
ATl(III)
BTl(I) over Tl(III) (s² pair retained)
CAlways higher oxidation
DSame oxidation
Answer & Solution
Correct answer: B. Tl(I) over Tl(III) (s² pair retained)
**Inert pair effect:** heavier 6th-period elements (Tl, Pb, Bi) prefer lower oxidation state with their s² pair untouched.
Tl(I), Pb(II), Bi(III) are more stable than Tl(III), Pb(IV), Bi(V).
Relativistic effects contribute.
Keep practising Unit 1C1: Periodic Trends in Atomic Properties
Browse all Unit 1C1: Periodic Trends in Atomic Properties questions for JEE Advanced, or explore more Chemistry topics.
Related questions
Match the formula to its IUPAC nameSort: p-block metal or non-metal?Spot the element that is NOT a noble gasWhich halogen liberates Cl₂ from solution of Cl⁻?PCl₅ in gas phase has shape:Ionization enthalpy comparison: O vs F. The 1st IE of O is LESS than that of N (because O Number of P-O-P bridges in P₄O₁₀:Reaction of XeF₂ with water: