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For pure water at 25 °C, K_w = 10⁻¹⁴. The concentration of OH⁻ in 10⁻³ M HCl is
A10⁻¹⁴ M
B10⁻³ M
C10⁻⁷ M
D10⁻¹¹ M
Answer & Solution
Correct answer: D. 10⁻¹¹ M
1. [H⁺] from HCl ≈ 10⁻³ M (water contribution negligible).
2. K_w = [H⁺][OH⁻] = 10⁻¹⁴, so [OH⁻] = 10⁻¹⁴ / 10⁻³.
3. [OH⁻] = 10⁻¹¹ M.
_Source: Maharashtra Balbharati Std XII Chemistry, Ch 3 "Ionic Equilibria" §3.6_
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