Practice free →
HomeNEET UGChemistry › Organic Chemistry

NEET UG Organic Chemistry — practice questions

104 free MCQs with worked solutions. Tap any question for the answer + explanation, or practice them all in the app.

Practice NEET UG Organic Chemistry in the app →
Choose the correct statementIn the following sets of compounds, the one which contains only medicinal compounds isThe $$\mathrm{pK}_{\mathrm{a}_1}$$ and $$\mathrm{pK}_{\mathrm{a}_2}$$ of an amino acid are 2.3 and 9.7 respectWhich of the following statements is not true?The Lassaigne's extract is boiled with conc. $$\mathrm{HNO_3}$$ while testing for halogens. By doing so itAbove reaction is an example of ![](https://qallery.app/diagrams/v2_248e9aa17a93/img-038.jpeg)The molecular formula of hexamethylene diammine adipate (monomer of nylon-66) isWhich of the following compounds is resistant to oxidation by periodic acid (HIO₄)?What will be the product in the following reaction ![](https://qallery.app/diagrams/v2_248e9aa17a93/img-034.jAn alkene, on ozonolysis gives formaldehyde and acetaldehyde. The alkene isBenzene on treatment with a mixture of conc. $$\mathrm{HNO_3}$$ and conc. $$\mathrm{H_2SO_4}$$ at $$100^{\circ$$\mathrm{CH_3-CH=CH-CH=CH-C_2H_5}$$ isWhich of the following resonating structures of 1-methoxy-1, 3-butadiene is least stableThe correct IUPAC name of the compound, ![](https://qallery.app/diagrams/v2_248e9aa17a93/img-033.jpeg)Nitrobenzene gives hydroxylamine by- ![](https://qallery.app/diagrams/v2_46c8b1655a73/img-013.jpeg)Given the diazonium salt shown, which product is formed on treatment with $NaNO_2$, Cu and heat? ![](https://In the following aromatic compound, bromination in presence of $Fe$ occurs preferentially at which labelled poOrder of boiling points of the given compound is: (1) pentan-1-ol (2) butan-1-ol (3) butan-2-ol (4) propan-1-According to VSEPR theory, the shape of a molecule is determined byThe hybridisation of carbon in methane (CH₄) isWhich molecule is non-polar despite having polar bonds?The bond order of the oxygen molecule O₂ (by molecular orbital theory) isA coordinate (dative) bond differs from a normal covalent bond in thatWhich species has sp hybridisation on the central atom?As bond order increases, bond lengthAn ionic bond forms byThe shape of NH₃ is pyramidal rather than planar becauseWhich has the highest dipole moment?Among the following, which is paramagnetic?Formal charge on an atom = Per NCERT §9.2, the general formula of an alkane (saturated open-chain hydrocarbon) is which?Per NCERT §9.2 + Fig 9.1, the H-C-H bond angle in methane and the carbon hybridisation are which?Per NCERT §9.2.2(2)(ii), the Wurtz reaction uses which reagent + solvent for coupling alkyl halides?Per NCERT §9.2.2(3)(i), heating CH₃COONa with NaOH + CaO (soda-lime) produces which gas?Per NCERT §9.2.2(3)(ii), in Kolbe electrolytic synthesis of alkanes, the alkane gas is liberated at which elecPer NCERT §9.2.3, the rate of HALOGENATION of alkanes (F₂, Cl₂, Br₂, I₂) decreases in which order?Per NCERT §9.2.3, the rate of substitution of HYDROGENS in alkane halogenation goes in which order (by carbon Per NCERT §9.2.3 Mechanism, the FIRST step of methane chlorination under sunlight is best described as which?Per NCERT §9.2.4, the STAGGERED conformation of ethane is more stable than the eclipsed conformation by approxPer NCERT §9.2.4, the STAGGERED form of ethane is more stable than ECLIPSED for which reason?Per NCERT §9.2.3 + Table 9.2, isomeric pentanes (n-pentane, 2-methylbutane, neopentane) have which boiling-poiPer NCERT §9.2.2(1), hydrogenation of an alkene to an alkane uses dihydrogen with which kind of catalyst?Per NCERT §9.3.1, in ethene the C-C bond consists of which σ/π combination, and the carbons are which hybridisPer NCERT §9.3.3, geometrical (cis-trans) isomerism in alkenes arises because of which feature of the double bPer NCERT §9.3.3, the dipole moment of cis-but-2-ene (0.33 D) and trans-but-2-ene (≈ 0 D) shows which form is Per NCERT §9.3.4(1), partial reduction of an alkyne to a CIS alkene uses which catalyst?Per NCERT §9.3.4(1), reduction of an internal alkyne with Na in LIQUID NH₃ gives which kind of alkene?Per NCERT §9.3.6 (Markovnikov rule, 1869), HBr addition to propene gives mainly which product?Per NCERT §9.3.6, the peroxide (Kharasch) effect on HBr addition to propene gives mainly which product?Per NCERT §9.3.6, the peroxide effect is observed only with which hydrogen halide?Per NCERT §9.3.6 (electrophilic addition mechanism), the rate-determining intermediate in HBr + propene additiPer NCERT §9.3.6, mild oxidation of an alkene with cold dilute KMnO₄ (Baeyer's reagent) gives which product?Per NCERT §9.3.6 (ozonolysis), reductive ozonolysis of an alkene with O₃ followed by Zn/H₂O gives which class Per NCERT §9.3.6, addition of conc. H₂SO₄ to an alkene followed by water gives mainly which class of compound?Per NCERT §9.4 (structure), the carbon-carbon triple bond in ethyne (HC≡CH) consists of which σ/π combination?Per NCERT §9.4.1, the C-H bond in ethyne is unusually ACIDIC because of which factor?Per NCERT §9.4.2, calcium carbide (CaC₂) reacts with water to give which gas?Per NCERT §9.4.2, dehalogenation of vicinal dihalide with alcoholic KOH gives which class of compound?Per NCERT §9.4.3 (acidic character), terminal alkynes react with sodium metal to liberate which gas + sodium aPer NCERT §9.4.3, addition of water to ethyne in dilute H₂SO₄ with HgSO₄ catalyst gives which final product?Per NCERT §9.4.3, addition of water to propyne under HgSO₄/H₂SO₄ gives mainly which product (Markovnikov)?Per NCERT §9.4.4 (cyclic polymerisation), three molecules of ethyne polymerise over a hot red-hot tube to givePer NCERT §9.4.3 (addition of HBr), HBr addition to propyne gives which Markovnikov product?Per NCERT §9.3.4(1), reduction of an alkyne to a TRANS alkene uses which reagent system?Per NCERT §9.4 (general formula), the general molecular formula of an open-chain alkyne is which?Per NCERT §9.4 (structure), the C-H bond in ethyne has shorter bond length than that in ethane because of whicPer NCERT §9.5.3, the THREE criteria for aromaticity (Hückel) are which set?Per NCERT §9.5.3, for benzene the value of n in Hückel's (4n+2) π electron formula is which?Per NCERT §9.5.2, all six C-C bond lengths in benzene are equal to approximately which value?Per NCERT §9.5.2, the carbon atoms of benzene are which hybridisation?Per NCERT §9.5.5, the FIVE common electrophilic substitution reactions of benzene are which set?Per NCERT §9.5.5 nitration, the actual ELECTROPHILE that attacks benzene in HNO₃ + H₂SO₄ mixture is which specPer NCERT §9.5.5 halogenation, the role of anhydrous AlCl₃ (or FeCl₃) in benzene chlorination is which?Per NCERT §9.5.5(iv), Friedel-Crafts ALKYLATION of benzene uses which reagent system?Per NCERT §9.5.5(v), Friedel-Crafts ACYLATION of benzene uses an acyl halide + AlCl₃ to generate which electroPer NCERT §9.5.5 (EAS mechanism), the carbocation intermediate formed during EAS on benzene is called which spPer NCERT §9.5.6, which of the following groups is a META-directing substituent on benzene?Per NCERT §9.5.6, halogens (-Cl, -Br) on benzene are which kind of directors despite their deactivating -I effThe general formula for alkanes is:Adding HBr to propene CH$_3$-CH=CH$_2$ in absence of peroxide gives mainly:Benzene satisfies Hückel's rule with $4n + 2$ pi electrons for $n =$:Nitration of toluene (methylbenzene) on the lab gives products mostly at:The property by which carbon bonds to other carbon atoms is:Who first synthesised acetic acid?In which year was acetic acid first synthesised?Methane was first synthesised by Berthelot in:An atom or group of atoms giving a compound its characteristic chemistry is a:Which of these is named as a functional group?The group written as CHO is the:The group written as COOH is the:Compounds sharing a characteristic functional group form a:A compound containing two or more functional groups is called:The modern system of naming organic compounds is abbreviated:In heterolytic cleavage, the shared pair of electrons stays with:After heterolysis, the positively charged atom has an electronic:A carbon bearing a sextet of electrons and a positive charge is a:Carbocations are classified as primary, secondary or:Which class of carbocation is the most stable?The shape of a carbocation is:The positively charged carbon of a carbocation is hybridised:Carbon in a carbanion is generally hybridised:The shape of a carbanion is described as a distorted:Homolytic cleavage of a bond produces:An electron-seeking species in a reaction is called an: