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According to Moseley's law, $\sqrt{\nu} = a(Z - b)$ for the characteristic X-ray lines. If two elements emit $K_\alpha$ X-rays with frequencies in the ratio $\nu_1 : \nu_2 = 4 : 9$, then their atomic numbers (ignoring screening $b$) satisfy

A$Z_1 : Z_2 = 2 : 3$
B$Z_1 : Z_2 = 4 : 9$
C$Z_1 : Z_2 = 3 : 2$
D$Z_1 : Z_2 = \sqrt{2} : \sqrt{3}$
Answer & Solution
Correct answer: A. $Z_1 : Z_2 = 2 : 3$
From $\sqrt{\nu} \propto Z$ (taking $b=0$ for ratio purposes), $\tfrac{Z_1}{Z_2} = \tfrac{\sqrt{\nu_1}}{\sqrt{\nu_2}} = \tfrac{\sqrt{4}}{\sqrt{9}} = \tfrac{2}{3}$.
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