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A nucleophilic addition reaction differs from a nucleophilic substitution reaction in that addition:
Atransfers an electron pair to form a ring
Breplaces one attached group with another
Cremoves two groups to create a multiple bond
Dadds across a multiple bond without losing a group
Answer & Solution
Correct answer: D. adds across a multiple bond without losing a group
1. Both reactions involve a nucleophile, an electron-rich species seeking a positive centre.
2. In nucleophilic addition the nucleophile adds across a multiple bond, and nothing leaves the molecule.
3. In nucleophilic substitution the nucleophile replaces a group already attached, which departs as a leaving group.
4. Removing two groups to create a multiple bond is elimination, a third reaction type entirely.
5. Explaining substitution when addition was asked for was the single most common recorded error on this question.
_Source: NECTA ACSEE 2024 Chemistry 132/1, Question 1: Aliphatic Hydrocarbons_
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