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Buffer capacity is maximum when:

ApH = pKa (equal acid and salt concentrations)
BpH > pKa
CpH < pKa
DpH = 7
Answer & Solution
Correct answer: A. pH = pKa (equal acid and salt concentrations)
Buffer capacity is maximum when [salt] = [acid], which means pH = pKa. The buffer can neutralise added acid or base most effectively at this point.
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