What does the molecularity of an elementary reaction count?
AThe number of reactant species taking part
BThe number of steps in the whole mechanism
CThe number of products the step gives out
DThe number of catalyst molecules involved
Answer & Solution
Correct answer: A. The number of reactant species taking part
1. Molecularity is a property of a single elementary step, not of a whole reaction.
2. It counts the reactant species, whether atoms, molecules or ions, that come together in that step.
3. One species makes the step unimolecular, two make it bimolecular and three make it termolecular.
4. Products are not counted, so a step giving two products is not automatically bimolecular.
_Source: OpenStax Chemistry (CC BY 4.0), Ch 12 "Kinetics", section 12.6 Reaction Mechanisms_
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