What is the root mean square speed of oxygen molecules at -23 degrees C? Molar mass is 0.032 kg/mol and R is 8.314 J/mol K.
A394 m/s
B441 m/s
C482 m/s
D225 m/s
Answer & Solution
Correct answer: B. 441 m/s
1. Apply the root mean square speed as the square root of 3RT divided by M.
2. Convert the temperature to kelvin: -23 + 273 = 250 K.
3. Build the numerator: 3 x 8.314 J/mol K x 250 K = 6235.5 J/mol.
4. Divide by the molar mass in kilograms per mole: 6235.5 / 0.032 = 1.949 x 10^5 m squared per second squared.
5. Take the square root: 441 m/s.
6. Oxygen is heavier than nitrogen and this sample is colder, so the answer must sit below the 519 m/s found for nitrogen at 30 degrees C.
7. Forgetting the Celsius to kelvin step would put a negative number under the square root, which has no meaning.
_Source: OpenStax Chemistry (CC BY 4.0), Ch 9 "Gases", section 9.5 The Kinetic-Molecular Theory_
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