A gas collected over water is a mixture. How is the pressure of the dry gas found?
AAdd the water vapour pressure to it
BSubtract the water vapour pressure
CHalve the total measured pressure
DMultiply by the water mole fraction
Answer & Solution
Correct answer: B. Subtract the water vapour pressure
1. A gas bubbled up through water arrives saturated with water vapour.
2. By Dalton's law the measured total is the gas pressure plus the water vapour pressure.
3. So the dry gas pressure is the total minus the vapour pressure of water at that temperature.
4. The vapour pressure depends only on the temperature, and is looked up in a table rather than calculated.
_Source: OpenStax Chemistry (CC BY 4.0), Ch 9 "Gases", section 9.3 Stoichiometry of Gaseous Substances, Mixtures, and Reactions_
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