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HomeMHT-CETChemistryCoordination Compounds › Which is an example of an **ambidentate** ligand?

Which is an example of an **ambidentate** ligand?

ACl⁻
BEDTA
CEthylenediamine
D$NO_2^-$ (can bind via N or via O)
Answer & Solution
Correct answer: D. $NO_2^-$ (can bind via N or via O)
Ambidentate = two possible donor atoms, but only one binds at a time. $NO_2^-$ binds via N (nitro) or O (nitrito); SCN⁻ binds via S (thiocyanato) or N (isothiocyanato). EDTA and en are polydentate (use multiple donors simultaneously), not ambidentate.
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