Home › JEE Advanced › Chemistry › Alcohols, Phenols and Ethers ›  Benzene is best described by:
AA resonance hybrid of two equivalent Kekulé structures
BA single Kekulé structure with alternating double bonds
CA non-planar buckled ring
DThree separated double bonds
Answer & Solution
Correct answer: A. A resonance hybrid of two equivalent Kekulé structures
Benzene's true bonding is a **resonance hybrid** of two equivalent Kekulé structures (the alternation of double bonds drawn either way). All six C-C bond lengths are equal (about $1.39$ Å, intermediate between a typical C-C single bond at $1.54$ Å and C=C double bond at $1.34$ Å).
The modern picture: six sp²-hybridised carbons form a planar hexagonal ring; each contributes one unhybridised $p$ orbital perpendicular to the ring. These overlap sideways to form a delocalised $\pi$ system (a doughnut of electron density above and below the ring).
Kekulé's original alternating-single-double picture (option A) underestimates the symmetry: the molecule has 6-fold rotational symmetry, which only the resonance/delocalised picture captures.
Related questions
With which two hydrogen halides is the peroxide effect not observed?Addition anti to Markovnikov rule is known as the peroxide or:Who framed the rule for adding HBr to unsymmetrical alkenes, in 1869?An intermediate conformation between eclipsed and staggered is called:Eclipsed and staggered conformations are represented by Newman and:Across all conformations, what stays the same?How many conformations can an alkane have by rotation about single bonds?Spatial arrangements interconverted by rotation about a single bond are called: