 Benzene is best described by:
AA resonance hybrid of two equivalent Kekulé structures
BA single Kekulé structure with alternating double bonds
CA non-planar buckled ring
DThree separated double bonds
Answer & Solution
Correct answer: A. A resonance hybrid of two equivalent Kekulé structures
Benzene's true bonding is a **resonance hybrid** of two equivalent Kekulé structures (the alternation of double bonds drawn either way). All six C-C bond lengths are equal (about $1.39$ Å, intermediate between a typical C-C single bond at $1.54$ Å and C=C double bond at $1.34$ Å).
The modern picture: six sp²-hybridised carbons form a planar hexagonal ring; each contributes one unhybridised $p$ orbital perpendicular to the ring. These overlap sideways to form a delocalised $\pi$ system (a doughnut of electron density above and below the ring).
Kekulé's original alternating-single-double picture (option A) underestimates the symmetry: the molecule has 6-fold rotational symmetry, which only the resonance/delocalised picture captures.
Related questions
Nitration of toluene (methylbenzene) on the lab gives products mostly at:Benzene satisfies Hückel's rule with $4n + 2$ pi electrons for $n =$:Adding HBr to propene CH$_3$-CH=CH$_2$ in absence of peroxide gives mainly:The general formula for alkanes is:According to Hückel's rule, a planar cyclic compound is aromatic if it has:Wurtz reaction is used to prepare:In the presence of organic peroxides, addition of HBr to propene gives predominantly:
When propene reacts with HBr,