Which one of the following reactions is not an example of redox reaction
A$\mathrm{HCl} + \mathrm{H}_2\mathrm{O} \rightarrow \mathrm{H}_3\mathrm{O}^- + \mathrm{Cl}$
B$\mathrm{Cu}^{++} + \mathrm{Zn} \rightarrow \mathrm{Zn}^{++} + \mathrm{Cu}$
C$2\mathrm{H}_2 + \mathrm{O}_2 \rightarrow 2\mathrm{H}_2\mathrm{O}$
D$\mathrm{Cl}_2 + 2\mathrm{H}_2\mathrm{O} + \mathrm{SO}_2 \rightarrow 4\mathrm{H}^+ + \mathrm{SO}^{4-} + 2\mathrm{Cl}^-$
Answer & Solution
Correct answer: A. $\mathrm{HCl} + \mathrm{H}_2\mathrm{O} \rightarrow \mathrm{H}_3\mathrm{O}^- + \mathrm{Cl}$
Check oxidation states. A reaction is not redox if there is no change in oxidation number.
In option $\mathrm{A}$, the process is essentially ionization of $\mathrm{HCl}$ in water. The oxidation numbers of $\mathrm{H}$ and $\mathrm{Cl}$ do not change, so it is not a redox reaction.
In option $\mathrm{B}$, $\mathrm{Zn}$ goes from $0$ to $+2$ and $\mathrm{Cu}^{2+}$ goes from $+2$ to $0$, so it is redox.
In option $\mathrm{C}$, $\mathrm{H}$ goes from $0$ to $+1$ and $\mathrm{O}$ goes from $0$ to $-2$, so it is redox.
In option $\mathrm{D}$, sulfur in $\mathrm{SO}_2$ goes from $+4$ to $+6$ and chlorine in $\mathrm{Cl}_2$ goes from $0$ to $-1$, so it is redox.
Therefore, the reaction which is not redox is option $\mathrm{A}$.
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