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MHT-CET Basic Principles of Organic Chemistry — practice questions — page 2

Explore 48 free Basic Principles of Organic Chemistry questions in MHT-CET Chemistry. Open each question or exercise to read its content, reference answers and available explanation.

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Basic Principles of Organic Chemistry questions and exercises with answers

Showing questions 31–48 of 48.

What is the hybridisation of the positively charged carbon in a carbocation?Read the answer and worked solution →Which orbital on a carbocation carbon is vacant?Read the answer and worked solution →Which order of carbocation stability is correct?Read the answer and worked solution →Which of these is an electrophile?Read the answer and worked solution →What is the nucleophilic centre of the nucleophile H2O?Read the answer and worked solution →In AlCl3, which atom is the electrophilic centre?Read the answer and worked solution →A bond between carbon and a more electronegative atom like chlorine is what type?Read the answer and worked solution →Polarity induced in adjacent C-C bonds by a polar bond is called which effect?Read the answer and worked solution →Which of these groups shows a -I effect?Read the answer and worked solution →Which halogen has the strongest -I effect?Read the answer and worked solution →Resonance theory applies to a system having which feature?Read the answer and worked solution →A single resonance structure of a molecule is considered to be what?Read the answer and worked solution →Which resonance structure is more stable and important?Read the answer and worked solution →What does the +R effect do to electron density at certain positions?Read the answer and worked solution →The -R effect develops what at certain positions in a molecule?Read the answer and worked solution →Hyperconjugation involves delocalisation of which electrons?Read the answer and worked solution →Hyperconjugation is also called what?Read the answer and worked solution →A larger number of alpha hydrogens gives what effect on stability?Read the answer and worked solution →

Worked practice questions

What is the hybridisation of the positively charged carbon in a carbocation?

  1. sp
  2. sp3
  3. dsp2
  4. sp2
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Correct answer: D. sp2

The carbocation carbon is sp2 hybridised with trigonal planar geometry and an empty p orbital.

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Which orbital on a carbocation carbon is vacant?

  1. 2s
  2. pz
  3. sp2
  4. 1s
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Correct answer: B. pz

The three sp2 orbitals form sigma bonds, leaving the unhybridised pz orbital empty and perpendicular to the plane.

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Which order of carbocation stability is correct?

  1. Primary > secondary > tertiary
  2. Tertiary > secondary > primary
  3. Secondary > tertiary > primary
  4. Tertiary > primary > secondary
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Correct answer: B. Tertiary > secondary > primary

More alkyl groups stabilise the positive charge, so (CH3)3C+ is more stable than secondary and primary.

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