As per your syllabus, Mechanism, the FIRST step of methane chlorination under sunlight is best described as which?
- Heterolysis of C-H bond
- Markovnikov addition
- Homolysis of Cl-Cl bond
- Wurtz coupling
Show answer and solution
Correct answer: C. Homolysis of Cl-Cl bond
syllabus Mechanism (i): Cl-Cl homolysis under hν gives two Cl• free radicals.
Free-radical chain mechanism.