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Water and toluene, being immiscible, form an azeotrope that boils

Aabove both pure liquids
Bbetween the two boiling points
Cbelow both pure liquids
Dexactly at water's boiling point
Answer & Solution
Correct answer: C. below both pure liquids
Immiscible liquids each add their own vapour pressure, so their azeotrope boils lower than either pure liquid.
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