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Nitrogen cannot reach the plus five state with halogens because it has no:

As-orbitals
Belectrons
Cd-orbitals
Dp-orbitals
Answer & Solution
Correct answer: C. d-orbitals
1. Reaching that state needs more orbitals than the second shell offers. 2. Nitrogen sits in the second period. 3. So it does not have d-orbitals available. _Source: syllabus Chemistry, Chapter 7, The p-Block Elements._
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