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Synergic bonding in metal carbonyls

Exercise and reference answers

Questions
  1. Question
    In a metal carbonyl, the ligand to metal bond is
    Choices
    1. a sigma bond
    2. a pi bond
    3. ionic
    Correct choice
    a sigma bond
  2. Question
    The metal to ligand bond is
    Choices
    1. a sigma bond
    2. a pi bond
    3. ionic
    Correct choice
    a pi bond
  3. Question
    This two-way arrangement is called
    Choices
    1. chelation
    2. ambidentate binding
    3. synergic bonding
    Correct choice
    synergic bonding
  4. Question
    Synergic bonding gives metal carbonyls
    Choices
    1. extra stability
    2. a permanent charge
    3. optical activity
    Correct choice
    extra stability

Explanation

The metal-carbon bond runs both ways: sigma from ligand to metal, pi from metal back to ligand. Source: syllabus Chemistry Part I, Ch 5 Coordination Compounds.
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