A mixture has Qc smaller than Kc. In which direction will the reaction proceed?
AToward the products, raising Qc up to Kc
BToward the reactants, cutting Qc down to Kc
CIn neither direction until heat is supplied
DToward whichever side has fewer particles
Answer & Solution
Correct answer: A. Toward the products, raising Qc up to Kc
1. Equilibrium requires Q to equal K, so any gap between them drives a shift.
2. If Q is below K the numerator is too small, meaning too little product is present.
3. Making more product raises Q until it matches K, so the shift is toward the products.
4. Shifting toward the reactants would lower Q further and widen the gap.
_Source: OpenStax Chemistry (CC BY 4.0), Ch 13 "Fundamental Equilibrium Concepts", section 13.3 Shifting Equilibria: Le Châtelier's Principle_
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