A Grignard reagent R-MgX reacts with **methanal (HCHO)** to produce, after hydrolysis:
AA secondary alcohol
BA ketone
CA tertiary alcohol
DA primary alcohol (R-CH₂-OH)
Answer & Solution
Correct answer: D. A primary alcohol (R-CH₂-OH)
**HCHO + RMgX → R-CH₂-OMgX → (H₂O) → R-CH₂-OH** (primary alcohol).
**General rule:** **HCHO
→ 1° alcohol; other RCHO
→ 2° alcohol; ketone → 3° alcohol**.
Powerful C-C bond-forming reaction.
Keep practising Alcohols, Phenols and Ethers
Browse all Alcohols, Phenols and Ethers questions for AP Intermediate 2nd Year, or explore more Chemistry topics.
Related questions
As per your syllabus, the carbon atoms of benzene are which hybridisation?As per your syllabus, all six C-C bond lengths in benzene are equal to approximately whichAs per your syllabus, for benzene the value of n in Hückel's (4n+2) π electron formula is As per your syllabus, the THREE criteria for aromaticity (Hückel) are which set?As per your syllabus, the general molecular formula of an open-chain alkyne is which?As per your syllabus, reduction of an alkyne to a TRANS alkene uses which reagent system?As per your syllabus, HBr addition to propyne gives which Markovnikov product?As per your syllabus, three molecules of ethyne polymerise over a hot red-hot tube to give