Start learning →

Among alkyl halides, the order of reactivity towards nucleophilic substitution (for the same R group) is:

AR-F > R-Cl > R-Br > R-I
BR-I > R-Br > R-Cl > R-F
CR-Cl > R-Br > R-I > R-F
DAll have identical reactivity
Answer & Solution
Correct answer: B. R-I > R-Br > R-Cl > R-F
**R-I > R-Br > R-Cl > R-F**. **Two reasons:** (i) **bond enthalpy decreases I > Br > Cl > F** (easier to break) (ii) **iodide is a better leaving group** because of polarisability/larger size — more stable as a free anion.
Practise this question with Quill — AP Intermediate 2nd Year →

Keep practising Haloalkanes and Haloarenes

Browse all Haloalkanes and Haloarenes questions for AP Intermediate 2nd Year, or explore more Chemistry topics.

Start a Haloalkanes and Haloarenes lesson →