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In a pseudo first order reaction, [A]/mol L^-1 reads 0.31 at t = 30 s and 0.17 at t = 60 s. What is the average rate of reaction over this interval in mol L^-1 s^-1?
A9.3 x 10^-3
B4.7 x 10^-3
C2.3 x 10^-3
D1.4 x 10^-2
Answer & Solution
Correct answer: B. 4.7 x 10^-3
1. Average rate $= -\dfrac{\Delta[A]}{\Delta t}$.
2. $\Delta[A] = 0.17 - 0.31 = -0.14\ \text{mol L}^{-1}$ over $\Delta t = 60 - 30 = 30\ \text{s}$.
3. Rate $= \dfrac{0.14}{30} = 4.7\times10^{-3}\ \text{mol L}^{-1}\text{s}^{-1}$.
4. Distractor D forgets to divide by the time interval; distractor C halves the result.
_Source: NCERT Class 12 Chemistry Ch 3 "Chemical Kinetics", p.24_
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