Ethanol reacts with $\mathrm{PCl_5}$ to give which set of products?
A$\mathrm{CH_3CH_2Cl} + \mathrm{POCl_3} + \mathrm{HCl}$
B$\mathrm{CH_3CH_3} + \mathrm{H_2O}$
C$\mathrm{CH_3CH_2OH \cdot HCl}$ (complex salt)
D$\mathrm{CH_3CHO} + \mathrm{H_2}$
Answer & Solution
Correct answer: A. $\mathrm{CH_3CH_2Cl} + \mathrm{POCl_3} + \mathrm{HCl}$
1. Your syllabus: $\mathrm{PCl_5}$ is a strong chlorinating agent that converts alcohols to alkyl chlorides.
2. Generic equation: $\mathrm{R{-}OH} + \mathrm{PCl_5} \to \mathrm{R{-}Cl} + \mathrm{POCl_3} + \mathrm{HCl}$.
3. For ethanol: $\mathrm{CH_3CH_2OH} + \mathrm{PCl_5} \to \mathrm{CH_3CH_2Cl} + \mathrm{POCl_3} + \mathrm{HCl}$.
4. All three by-products are formed: ethyl chloride (the substitution product), phosphoryl chloride (from $\mathrm{PCl_5}$ losing $\mathrm{Cl}$ and gaining $\mathrm{O}$), and HCl gas.
5. Option B describes a different reaction. Option C is a salt that doesn't form. Option D is dehydrogenation, not happening here.
_Source: syllabus Chemistry Part 2, Ch 7, §7.4 (Conversion of alcohols to alkyl halides — $\mathrm{PCl_5}$, $\mathrm{PCl_3}$, $\mathrm{SOCl_2}$), p. 12–13._
Keep practising Haloalkanes, Alcohols and Ethers
Browse all Haloalkanes, Alcohols and Ethers questions for AP Intermediate 2nd Year, or explore more Chemistry topics.
Related questions
The KOLBE reaction converts phenol (in the form of sodium phenoxide) into salicylic acid. Ethanol reacts with $\mathrm{PCl_5}$ to give which set of products?NEET · Chemistry · Primary or Secondary AlcoholA GRIGNARD REAGENT is formed by reacting an alkyl halide withThe IUPAC name of $\mathrm{(CH_3)_2CH{-}CH_2Br}$ isThe reaction of ethanol with sodium metal producesThe reactivity of haloalkanes toward nucleophilic substitution generally follows the orderThe REIMER-TIEMANN reaction converts phenol to salicylaldehyde. The reagents are