A buffer solution:
AHas pH exactly 7
BHas pH > 14
CHas no equilibrium
DResists changes in pH on adding small acid or base
Answer & Solution
Correct answer: D. Resists changes in pH on adding small acid or base
### What is a Buffer Solution?
A **buffer solution** is an aqueous solution consisting of a mixture of a weak acid and its conjugate base, or a weak base and its conjugate acid. Its primary purpose is to resist changes in hydrogen ion concentration ($pH$) when small amounts of acid or base are added to it.
### How it Works
Consider an acidic buffer made of acetic acid ($CH_3COOH$) and its conjugate base, acetate ($CH_3COO^-$):
1. **Adding Acid ($H^+$):** The added $H^+$ ions react with the conjugate base to form more weak acid:
$$CH_3COO^- + H^+ \rightarrow CH_3COOH$$
This prevents the $H^+$ concentration from increasing significantly.
2. **Adding Base ($OH^-$):** The added $OH^-$ ions react with the weak acid to form the conjugate base and water:
$$CH_3COOH + OH^- \rightarrow CH_3COO^- + H_2O$$
This prevents the $OH^-$ concentration from increasing significantly.
### Conclusion
Because the added ions are effectively "neutralized" by the buffer components, the $pH$ of the solution remains relatively stable. Therefore, the correct option is **D** D**.
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