The ratio of the longest wavelength in the Lyman series to the longest wavelength in the Balmer series of hydrogen is
A$\tfrac{5}{27}$
B$\tfrac{1}{4}$
C$\tfrac{4}{1}$
D$\tfrac{27}{5}$
Answer & Solution
Correct answer: A. $\tfrac{5}{27}$
Longest wavelength in a series corresponds to the smallest energy jump: $n=2 \to 1$ for Lyman, $n=3 \to 2$ for Balmer.
Using $\tfrac{1}{\lambda} = R\left(\tfrac{1}{n_1^2} - \tfrac{1}{n_2^2}\right)$: Lyman max gives $\tfrac{1}{\lambda_L} = R(1 - \tfrac{1}{4}) = \tfrac{3R}{4}$.
Balmer max gives $\tfrac{1}{\lambda_B} = R(\tfrac{1}{4} - \tfrac{1}{9}) = \tfrac{5R}{36}$.
Ratio $\tfrac{\lambda_L}{\lambda_B} = \tfrac{5R/36}{3R/4} = \tfrac{5}{36} \cdot \tfrac{4}{3} = \tfrac{20}{108} = \tfrac{5}{27}$.
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