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Per NCERT §9.5.5(v), Friedel-Crafts ACYLATION of benzene uses an acyl halide + AlCl₃ to generate which electrophile?
ACarbanion R⁻ alone
BCarbene R₂C: alone
CAcylium (RC⁺=O ion)
DFree-radical R• alone
Answer & Solution
Correct answer: C. Acylium (RC⁺=O ion)
NCERT §9.5.5(v): RCOCl + AlCl₃ → RC⁺=O + AlCl₄⁻ (acylium ion attacks benzene to give acyl benzene).
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