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The Henry's law constant of CH₃Br in water at 25 °C is 0.159 mol L⁻¹ bar⁻¹. The solubility of CH₃Br at 25 °C and a partial pressure of 130 mm Hg is approximately:

A2.7 M
B0.27 M
C0.027 M
D20.7 M
Answer & Solution
Correct answer: B. 0.27 M
Convert: $P = 130/760$ atm $= 0.171$ atm $\times 1.013$ bar/atm $= 0.173$ bar. $S = K_H P = 0.159 \times 0.173 \approx 0.275$ M $\approx 0.27$ M.
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