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The role of a salt bridge in a galvanic cell is to:
AAllow electrons to flow between the half cells
BProvide the EMF of the cell
CIncrease the rate of reaction at the electrodes
DMaintain electrical neutrality of the two solutions and complete the circuit by ionic conduction
Answer & Solution
Correct answer: D. Maintain electrical neutrality of the two solutions and complete the circuit by ionic conduction
The external wire carries the electrons; the salt bridge carries ions between the two half-cell solutions. Without it, accumulation of positive ions around the anode and negative ions around the cathode would polarise the cell and the current would stop. The salt bridge neutralises this build-up by supplying inert ions (typically $\mathrm{K^+}$ and $\mathrm{NO_3^-}$) and completes the electrical circuit.
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