 A **tetrahedral void** in a close-packed crystal has coordination number:
A8
B4
C2
D6
Answer & Solution
Correct answer: B. 4
A tetrahedral void is the cavity formed at the centre of four spheres arranged at the vertices of a tetrahedron. **Coordination number is 4** (each surrounded by 4 neighbours).
For a sphere to fit a tetrahedral void: $r_{\text{void}} = 0.225 \times r_{\text{sphere}}$ (the **radius ratio**).
Compare with **octahedral voids** (option C): surrounded by 6 spheres, $r_{\text{void}} = 0.414 \times r_{\text{sphere}}$. Larger ions (like $\mathrm{Na^+}$ in $\mathrm{NaCl}$) fit octahedral voids; smaller ones (like $\mathrm{Zn^{2+}}$ in $\mathrm{ZnS}$) fit tetrahedral.
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