NF3 has a much smaller dipole moment than NH3 because
- NF3 has a planar geometry overall
- N–F bonds have no polarity at all
- fluorine has a lower atomic number
- lone pair dipole opposes bond dipoles
Show answer and solution
Correct answer: D. lone pair dipole opposes bond dipoles
In NF3 the lone pair dipole points against the N–F bond dipoles and cancels part of them, unlike in NH3.