**Dehydration** of alcohols to alkenes with concentrated H₂SO₄ follows the order:
- 1° > 2° > 3°
- 3° > 2° > 1° (more stable carbocation favours E1)
- All equal
- Aromatic > aliphatic
Show answer and solution
Correct answer: B. 3° > 2° > 1° (more stable carbocation favours E1)
**E1 dehydration:** more stable carbocation forms faster.
3° (most stable cation, lowest activation E) > 2° > 1°.
Tertiary alcohols dehydrate even at lower temperatures (~20% H₂SO₄, ~85 °C)
primary need conc. H₂SO₄, ~170 °C.