Which complex would exhibit **optical isomerism**?
- $[Pt(NH_3)_2Cl_2]$ (square planar)
- $[Co(NH_3)_6]^{3+}$
- **cis**-$[Co(en)_2Cl_2]^+$ (chiral)
- **trans**-$[Co(en)_2Cl_2]^+$
Show answer and solution
Correct answer: C. **cis**-$[Co(en)_2Cl_2]^+$ (chiral)
Only cis-$[Co(en)_2Cl_2]^+$ lacks a mirror plane (it's chiral).
The trans isomer has a $C_2$ axis and a mirror plane → achiral.
Homoleptic $[Co(NH_3)_6]^{3+}$ is highly symmetric → achiral.
Square planar geometries typically are achiral.