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Both carboxylic acids and esters contain a carbonyl group with a second oxygen atom bonded to the carbonyl carbon. What differs between the two?
AEsters always contain additional nitrogen atoms
BCarboxylic acids do not actually contain any carbonyl group
CEsters are always gaseous at ordinary room temperature
DIn an acid the second oxygen bonds to hydrogen; in an ester, to carbon
Answer & Solution
Correct answer: D. In an acid the second oxygen bonds to hydrogen; in an ester, to carbon
1. Both functional groups are built on the same carbonyl-plus-extra-oxygen framework, so the distinction lies in what that second oxygen attaches to.
2. The text explains: "In a carboxylic acid, the second oxygen atom also bonds to a hydrogen atom. In an ester, the second oxygen atom bonds to another carbon atom."
3. Neither group contains nitrogen, both clearly do contain a carbonyl group by definition, and esters are typically liquids (e.g. fruit-scented esters), not gases.
4. So the difference comes down to whether that second oxygen bonds to hydrogen (acid) or carbon (ester).
_Source: OpenStax Chemistry Ch 20 "Organic Chemistry", p.1124 §20.3 Aldehydes, Ketones, Carboxylic Acids, and Esters_
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