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In an Ellingham diagram the line for the formation of carbon monoxide ($2C + O_2 ightarrow 2CO$) has a negative slope. This indicates that
ACO becomes less stable as temperature rises
Bthe reaction is endothermic
Ccarbon cannot reduce any oxide
DCO becomes more stable as temperature rises
Answer & Solution
Correct answer: D. CO becomes more stable as temperature rises
1. Slope of an Ellingham line is $-\Delta S^\circ$.
2. Forming 2 mol of CO gas from 1 mol $O_2$ increases the number of gas moles, so $\Delta S^\circ$ is positive and the slope $-\Delta S^\circ$ is negative.
3. A downward line means $\Delta G^\circ$ keeps decreasing with T, so **CO grows more stable at higher temperature** — this is why carbon is an excellent reducing agent at high T.
_Source: Samacheer Kalvi Class 12 Chemistry Vol.1, Unit 1 'Metallurgy', §1.4.1 (observations) / Evaluation Q.23_
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