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Ethanol heated with concentrated $\mathrm{H_2SO_4}$ at $443\,\text{K}$ (170°C) gives mainly
Adiethyl ether (ether at lower T)
Bethanal (mild oxidation)
Csodium ethoxide
Dethene (alkene via dehydration)
Answer & Solution
Correct answer: D. ethene (alkene via dehydration)
1. NCERT §7.4 (Dehydration of alcohols): concentrated $\mathrm{H_2SO_4}$ is a strong dehydrating agent.
2. At HIGH TEMPERATURE ($\sim 443\,\text{K}$), the dominant reaction is INTRAMOLECULAR DEHYDRATION: removal of an $\mathrm{H}$ and an $\mathrm{OH}$ from adjacent carbons within ONE molecule of ethanol, giving an ALKENE.
3. $\mathrm{CH_3CH_2OH} \xrightarrow{\text{conc.}\,\mathrm{H_2SO_4}, 443\,\text{K}} \mathrm{CH_2{=}CH_2} + \mathrm{H_2O}$.
4. Product is ETHENE (ethylene).
5. At LOWER temperature ($\sim 413\,\text{K}$ / 140°C), INTERMOLECULAR dehydration dominates: two alcohol molecules lose ONE water, giving an ETHER ($\mathrm{CH_3CH_2{-}O{-}CH_2CH_3}$, diethyl ether). So option A is at LOWER T.
6. Options B and C describe unrelated reactions.
_Source: NCERT Class 12 Chemistry Part 2, Ch 7, §7.4 (Dehydration of alcohols — temperature-dependent products), p. 11–12._
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