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According to collision theory, for a chemical reaction to occur, colliding molecules must possess
Athe lowest possible kinetic energy, since cold molecules react more efficiently
Bexactly equal kinetic energies for both colliding partners
Cenergy below the threshold, since high energy destroys reactants
Denergy at or above the activation energy, AND a suitable orientation
Answer & Solution
Correct answer: D. energy at or above the activation energy, AND a suitable orientation
1. NCERT §3.6 (Collision Theory) gives two conditions for a successful (productive) collision.
2. ENERGY: the kinetic energy of the colliding molecules must equal or exceed the activation energy $E_a$ (the threshold) so that bonds can break.
3. ORIENTATION: the molecules must collide along an axis that allows the relevant bonds to form/break — this is captured by the steric factor $p$ in the Arrhenius pre-exponential $A$.
4. So a successful collision needs BOTH: sufficient energy AND correct geometry. Most collisions fail one or both tests, which is why measured rate constants are much smaller than the collision frequency.
5. Option A reverses the energy requirement. Option C is irrelevant (it's the SUM of energies relative to $E_a$ that matters, not individual values). Option D is plainly wrong — high energy enables, not hinders, reaction.
_Source: NCERT Class 12 Chemistry Part 1, Ch 3, §3.6 (Collision Theory of Chemical Reactions), p. 22–23._
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