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The Arrhenius equation $k = A\,e^{-E_a/RT}$ predicts that, at a given temperature, increasing the ACTIVATION ENERGY $E_a$ will
AINCREASE the rate constant exponentially
BDECREASE the rate constant exponentially
Chave no effect — only $T$ controls $k$
Dlinearly increase $k$ proportional to $E_a$
Answer & Solution
Correct answer: B. DECREASE the rate constant exponentially
1. NCERT §3.5 introduces the Arrhenius equation: $k = A\,e^{-E_a/RT}$.
2. At fixed $T$, the exponential term $e^{-E_a/RT}$ DECREASES as $E_a$ increases, because the argument $-E_a/RT$ becomes more negative.
3. So a higher activation barrier makes the reaction slower at the same temperature — exponentially slower.
4. This is WHY a catalyst (which lowers $E_a$) speeds up reactions so dramatically: a modest drop in $E_a$ can change $k$ by orders of magnitude through the exponential.
5. Option A reverses the dependence. Option C ignores the $E_a$ term entirely. Option D would be a LINEAR (not exponential) dependence.
_Source: NCERT Class 12 Chemistry Part 1, Ch 3, §3.5 (Temperature Dependence of the Rate — Arrhenius Equation), p. 18–19._
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