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In the reaction $\mathrm{H}_2\mathrm{S}(g) + \mathrm{Cl}_2(g) \rightarrow 2\mathrm{HCl}(g) + \mathrm{S}(s)$, which species undergoes oxidation?
A$\mathrm{H}_2\mathrm{S}$, because chlorine (more electronegative) is added to its hydrogen
B$\mathrm{Cl}_2$, because it gains hydrogen from $\mathrm{H}_2\mathrm{S}$
CBoth $\mathrm{H}_2\mathrm{S}$ and $\mathrm{Cl}_2$, by an equal extent
DNeither species — this is not a redox reaction
Answer & Solution
Correct answer: A. $\mathrm{H}_2\mathrm{S}$, because chlorine (more electronegative) is added to its hydrogen
1. Track oxidation numbers. In $\mathrm{H}_2\mathrm{S}$, S is $-2$; in product S(s), S is $0$. So S goes from $-2 \rightarrow 0$, an INCREASE in oxidation state.
2. Increase in oxidation state is the modern definition of oxidation.
3. Equivalently (classical view), $\mathrm{H}_2\mathrm{S}$ loses hydrogen to chlorine (a more electronegative element), so it is oxidised.
4. $\mathrm{Cl}_2$ goes from $0 \rightarrow -1$ in HCl, a DECREASE, i.e. reduction (option B reverses this).
5. Since both half-reactions occur simultaneously, the reaction IS redox, ruling out option D. Option C is wrong because only S is oxidised; Cl is reduced.
_Source: NCERT Class 11 Chemistry Part 2, Ch 7, Problem 7.1 (i), p. 1–2._
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