Pent-$2$-ene is treated with hot, acidic KMnO$_4$. What are the products?
AAcetic acid + propanoic acid
BPentane-$2{,}3$-diol
CPentanoic acid + water
DPent-$2$-en-$1$-ol
Answer & Solution
Correct answer: A. Acetic acid + propanoic acid
**Reagent behaviour.** *Cold, dilute* KMnO₄ (Baeyer's reagent) gives the diol — that's option D. *Hot, acidic* KMnO₄ is much more aggressive: it oxidatively cleaves the double bond, giving carboxylic acids (or CO₂ if the carbon was terminal).
**Apply to pent-2-ene.** $\mathrm{CH_3-CH=CH-CH_2-CH_3}$. Cleaving the C2=C3 bond, each side becomes its own acid:
- Left ($\mathrm{CH_3-CH}=$) → acetic acid $\mathrm{CH_3COOH}$.
- Right ($=\mathrm{CH-CH_2-CH_3}$) → propanoic acid $\mathrm{CH_3CH_2COOH}$.
**Why option D is tempting.** It's the *cold* dilute KMnO₄ answer (syn-diol). Read the reagent conditions carefully — temperature and acidity decide which product surfaces.
Related questions
Besides VSEPR and the Kossel Lewis approach, which two theories are listed?Which theory is abbreviated VSEPR?Why can lattice enthalpy not be calculated directly from attraction and repulsion alone?Ionic bonds form most easily between elements with low ionization enthalpies and high negaWhat is the lattice enthalpy of sodium chloride?Lattice enthalpy is the energy required to separate one mole of an ionic solid into:The structures contributing to a resonance hybrid are called:Why was the concept of resonance introduced?