For the gas-phase reaction $2\mathrm{SO_2(g)} + \mathrm{O_2(g)} \rightleftharpoons 2\mathrm{SO_3(g)}$, the value of $\Delta n$ (used in $K_p = K_c (RT)^{\Delta n}$) is
A$+1$
B$0$
C$+2$
D$-1$
Answer & Solution
Correct answer: D. $-1$
1. $\Delta n = $ (moles of GASEOUS products) − (moles of GASEOUS reactants).
2. Products: 2 mol $\mathrm{SO_3(g)}$.
3. Reactants: 2 mol $\mathrm{SO_2(g)} + 1$ mol $\mathrm{O_2(g)} = 3$ mol.
4. $\Delta n = 2 - 3 = -1$.
5. Therefore $K_p = K_c (RT)^{-1}$, i.e. $K_p < K_c$ at usual temperatures (since $RT > 1$ when $R$ is in $\text{L\,bar/(K\,mol)}$ and $T$ in K).
6. Option A flips the sign. Option B would apply if products and reactants had equal gas-mole sums. Option C would correspond to $4$ products and $2$ reactants.
_Source: syllabus Chemistry, Ch 6, §6.4.1 (Eq. 6.15 with $\Delta n$ definition), p. 11._
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