For a gas-phase reaction at temperature $T$, the relationship between the equilibrium constants $K_p$ (in partial pressures) and $K_c$ (in molar concentrations) is
A$K_p = K_c\,(RT)^{\Delta n}$
B$K_p = K_c\,(RT)^{-\Delta n}$
C$K_p = K_c / (\Delta n)$
D$K_p$ and $K_c$ are always equal
Answer & Solution
Correct answer: A. $K_p = K_c\,(RT)^{\Delta n}$
1. NCERT §6.4.1 derives the relationship for an ideal-gas reaction $aA + bB \rightleftharpoons cC + dD$.
2. Use the ideal-gas law $p = (n/V)RT = [X]RT$ to substitute partial pressure for concentration.
3. The result (Eq. 6.15): $K_p = K_c\,(RT)^{\Delta n}$, where $\Delta n = (c + d) - (a + b)$ is the change in moles of gaseous species (products minus reactants).
4. When $\Delta n = 0$ (e.g. $\mathrm{H_2 + I_2 \rightleftharpoons 2HI}$), $K_p = K_c$. Otherwise they differ by a power of $RT$.
5. Option B inverts the exponent. Option C is dimensionally wrong. Option D is only true for $\Delta n = 0$.
_Source: NCERT Class 11 Chemistry, Ch 6, §6.4.1 (Eq. 6.15), p. 10–11._
Related questions
Acetic acid together with sodium acetate acts as a:Suppressing ionisation by adding an ion already present is the:A NaOH solution with a hydronium concentration of 10 to the minus 10 M has a pH of:A solution with a hydrogen ion concentration of 10 to the minus 7 M has a pH of:The pH of a solution is defined as the negative logarithm to base:The pH scale is:Thomas M. Lowry was a chemist from:A Bronsted-Lowry acid is a substance capable of donating: