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For the reaction $2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g)$, the relationship between $K_p$ and $K_c$ is:
A$K_p = K_c \cdot (RT)$
B$K_p = K_c \cdot (RT)^2$
C$K_p = K_c$
D$K_p = \dfrac{K_c}{RT}$
Answer & Solution
Correct answer: D. $K_p = \dfrac{K_c}{RT}$
General relation: $K_p = K_c \cdot (RT)^{\Delta n}$, where $\Delta n$ is the change in gas-phase moles, $n_{products} - n_{reactants}$.
For the SO₂ oxidation: products $2$ mol of SO₃; reactants $2 + 1 = 3$ mol. So $\Delta n = 2 - 3 = -1$.
$K_p = K_c \cdot (RT)^{-1} = \dfrac{K_c}{RT}$.
Quick sanity rule: when products have fewer gas moles than reactants, $K_p < K_c$ (at usual conditions where $RT > 1$). Option D would require $\Delta n = +2$, which would mean two more product gas moles than reactant.
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